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The persulfide anion is expected to react faster than a thiolate of equal basicity, according to the alpha effect ( acting as nucleophiles form products that contain two electrophilic sulfur atoms (Figure 1), which make it possible to recover the thiol species by a subsequent nucleophilic attack to the original outer sulfur
PMID 28627191
J.BaxterM
The peptide corresponds to the sequence Gly-Glu-Pro-Pro-Pro-Gly-Lys-Pro-Ala-Asp-Asp-Ala-Gly-Leu-Val
Yoo C, Xing D, Gonzalez DE, Jenkins V, Nottingham K, Dickerson B, et al
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