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There are several points of the TCA cycle that are critical for NRF2-regulated processes

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The reductive half-reaction of the SmTGR H571A variant As previously stated, kinetic studies of U597C SmTGR variant and the data shown above for the C159S variant implicate that an intense, broad charge transfer, which we have typically observed at 540 nm, is the result of the proximity of the C159 thiolate and oxidized FAD isoalloxazine (Smith et al., 2023)

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