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However, when these defenses are compromised, excess Fe + mediates Fenton reactions that generate hydroxyl radicalshighly reactive species that oxidize polyunsaturated fatty acids (PUFAs) in phospholipids

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So to say glutathione is an important molecule for human health would be a bit of an understatement

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Role of diet in the risks of esophageal adenocarcinoma and squamous cell carcinoma: an updated umbrella review