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10.1038/s41419-017-0033-4 383 YoshinoJ.BaurJ

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The copper ions can oxidize ascorbic acid while the acid destabilizes the peptide-copper bond

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Subsequent work established that the same sequence exists in human plasma, saliva, and urine at concentrations that decline with age, and that the sequence is found as a subfragment of the alpha-2 chain of type I collagen, which means GHK is released into the tissue environment when collagen breaks down