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doi:10.2147/CCID.S127361 Study: Antioxidants like glutathione preserve collagen, reducing fine lines and wrinkles

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They showed that doses above 400 mg/kg caused an almost complete exhaustion of GSH levels in the liver and a sharp rise in the amount of covalent binding (Figure6B)

Assay of glutathione, glutathione disulfide, and glutathione mixed disulfides in biological samples

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"Purification and steady-state kinetic analysis of yeast thiosulfate reductase"