10.1111/j.1749-6632.1993.tb39148.x
This was attributed to the ability of the methoxy group to stabilize the increasing positive charge at the selenium atom during the ratedetermining step of the catalytic cycle, which involves the oxidation of Se(II) to Se(IV), thus improved their catalytic activity to levels comparable with their aliphatic counterparts [56]
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"Mechanistic studies on a novel, highly potent gold-phosphole inhibitor of human glutathione reductase"
Although the concentrations of Cr used in this study are high, similar concentrations were used previously by other workers [14,15,61]
Substrate promiscuity and hyperoxidation susceptibility as potential driving forces for the co-evolution of Prx5-Type and Prx6-Type 1-Cys peroxiredoxin mechanisms